By J. S. Fruchter, C. L. Wilkerson, J. C. Evans, R. W. Sanders (auth.), Royston H. Filby, B. Stephen Carpenter, Richard C. Ragaini (eds.)
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Additional info for Atomic and Nuclear Methods in Fossil Energy Research
R. Silyerman, Amer. Chern. Soc. , Di'V. Petro Chern. Preprints :14: (3) E-32 (1969):- :19. M. popl, V. Dolansky, G, Sebor, M. ~. - Geol. ~· 20.. M. M. Bean, Chern. Eng. 21. G. V. Whitehead, Amer. , Div, petro Chem. Preprints 25;268 (198~ ~ - - 22. H. R. Shah, Proc. Amer. Nucl. Soc. Conf. on Nucl. Meth. in Environ. , p68, Columbia Univ. oflMo. 71). , 7:269 (1962),- 47 TRACE ELEMENTS IN PETROLEUM 23. -- 24. D. A. Lubkowitz, 25. O. Larson, Anal. Chern. 47:1159 (1975) 26. A. I. H. , "Analysis of Petroleum for Trace Metals" Chap.
Assuming that only porphyrinic metals are eluted, a value of 45% of Ni porphyrin and 46% of vanadyl porphyrin was obtained for a Kuwait residue. These values are much higher than the figure of 14% measured by absorption spectrophotometry. These facts clearly reveal that much work has still to be done and special efforts need to be concentrated in better separation methods with concomitant reliable analytical techniques for quantitation. On the other hand, the variance of V/Ni porphyrins in crudes may also suggest that the two metals were incorporated independently during the diagenesis and maturation processes.
Pure Appl. , 15:345 (1977). ~. Radioanal. Chern. - -- ~. ~. -- Radioanal. Chern. 38:267 Radioanal. Chern. 27:439 (1975). ~. ~. Radioanal. Appl. Rad. Isotop. D. BUENAFAMA 48 46. H. Meier, E. Unger, 47. L. A. Wilson, E,P. J. Coleman, port 1977 BERC/RI - 77/8 (1977), 48. G. Sebor, I. Lang, 49. I. Lang, G. Sebor, V. Sychra, D. Kolikova, Chern. Acta, 84:299 (1976). 50. A. Nadkarni, Anal. Chem. 521929 (1980). 51. M. H. K. E. A. H. H. R. C. Ragaini, Anal. Chem. 43:1102 (1975). 52. R. Bonnet, F. Czechowski, Nature, 283:465 (1980).
Atomic and Nuclear Methods in Fossil Energy Research by J. S. Fruchter, C. L. Wilkerson, J. C. Evans, R. W. Sanders (auth.), Royston H. Filby, B. Stephen Carpenter, Richard C. Ragaini (eds.)