Download e-book for kindle: Basic Materials Studies by P N Peapell and J A. Belk (Auth.)

By P N Peapell and J A. Belk (Auth.)

ISBN-10: 0408013745

ISBN-13: 9780408013741

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Size factor differences of greater than 14% have been seen to lead to restricted primary solubility, but larger size differences give particular types of intermetallic compound. 2 0 % to 3 0 % size differences occur in Laves phases although size difference is not the only criterion for their formation. 59 give rise to interstitial c o m p o u n d s of simple structure such as T i C which has the NaCl structure. 41 occur in interstitial solid solutions. Electrochemical c o m p o u n d s are m o r e difficult to predict as although stable c o m p o u n d s such as Mg 2Si arise from atoms with a large difference in electro-negativity, other factors are also important.

T h e structure of the program is identical but the variable, S, is now the sum of the products of the atomic percents and atomic weights. T h e line 620 where the weight percent is calculated is of a slightly different form from line 430. 5 HUME-ROTHERY PRIMARY SOLID SOLUBILITY PAGE PRINT "This is a simple application o-f the Hume-Rothery" PRINT "rales for primary solubility. " PRINT PRINT "List all the available metals? " 1000 PRINT 1010 RESTORE 1020 GO TO 550 1030 END Program notes (1) T h e three H u m e - R o t h e r y rules for primary solid solubility are 36 Basic Materials Studies applied by the program to data on each of the two elements forming the alloy and an indication is given of the likely extent of primary solubility.

E. above 300 K, C p and C v can be taken as equal. 7) where A is a constant, Q is the activation energy and T i s the absolute t e m p e r a t u r e . T h e activation energy is the energy that must be supplied in o r d e r that a reaction might proceed. 2. W h e n the block is in Position 1, its potential energy, Ex = mghx. In Position 3 its potential energy, E3, is lower and = mgh3. T h u s , in going from Position 1 to Position 3 , an energy of — mg {hx — h3) is released. 2 Activation energy — mechanical analogue.

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Basic Materials Studies by P N Peapell and J A. Belk (Auth.)


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