Read e-book online Handbook of carbon, graphite, diamond, and fullerenes: PDF

By Hugh O. Pierson

ISBN-10: 0815513399

ISBN-13: 9780815513391

This publication is a overview of the technology and expertise of the point carbon and its allotropes: graphite, diamond and the fullerenes. This box has improved drastically within the final 3 a long time inspired by way of many significant discoveries reminiscent of carbon fibers, low-pressure diamond, and the fullerenes. the necessity for any such booklet has been felt for a while. those carbon fabrics are very diversified in constitution and homes. a few are very outdated (charcoal), others fresh (the fullerenes). they've got diverse functions and markets and are produced by way of assorted segments of the industry.

Few reviews can be found that try and assessment the full box of carbon as a complete self-discipline. additionally those reviews have been written numerous a long time in the past and a commonly outmoded because the improvement of the know-how is relocating very quickly and scope of functions is consistently increasing and achieving into new fields reminiscent of aerospace, car, semiconductors, optics, and electronics. during this e-book the writer presents a necessary, up to date account of either the more recent and standard different types of carbon, either certainly happening and man-made. This quantity should be a important source for either experts in, and low clients of carbon fabrics.

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Additional resources for Handbook of carbon, graphite, diamond, and fullerenes: properties, processing, and applications

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The Carbon Hybrid sp 3 Orbital. The 1s22s22p2 configuration of the carbon atom does not account for the tetrahedral symmetry found in structures such as diamond or methane (CH4) where the carbon atom is bonded to four other carbon atoms in the case of diamond, or to four atoms of hydrogen in the case of methane. In both cases, the four bonds are of equal strength. 6. Schematic representation of the "s" and "p" orbitais. with its spin uncoupled from the other electrons. This alteration occurs as a result of the formation of hybrid atomic orbitais, in which the arrangement of the electrons of the L shell of the atom in the ground state is modified as one of the 2s electron is promoted (or lifted) to the higher orbital 2p as shown in Fig.

This overlap is similar to the sp3 overlap illustrated in Fig. 7. Like the sp3 orbital, the sp2 is directional and is called a sigma (a) orbital, and the bond a sigma bond. The Element Carbon 35 Each sp2-hybridized carbon atom combines with three other sp2-hybridized atoms to form a series of hexagonal structures, all located in parallel planes as shown schematically in Fig. 16. The fourth valency, that is, the free delocalized electron, is oriented perpendiculartothis plane as illustrated in Fig.

A. , Advanced Inorganic Chemistry, Interscience Publishers, New York (1972) 7. , CRC Press, Boca Raton, FL (1985) 8. Press, F. H. , San Francisco (1974) 9. , Understanding Physics, Vol. 3, Dorset Press (1988) 10. , 69(10) :1639 (1990) 11. Krauskopf, K. , New York (1967) 12. Huheey, J. , Inorganic Chemistry, 3rd. , Harper & Row, New York (1983) 13. , Advanced Inorganic Chemistry, John Wiley & Sons, New York (1985) 14. Korshak, V. , et al, Carbon, 25(6):735-738 (1987) 15. Palmer, H. B. , Chemistry and Physics of Carbon, (P.

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Handbook of carbon, graphite, diamond, and fullerenes: properties, processing, and applications by Hugh O. Pierson

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