By M.T. Pope, Achim Müller
An authoritative up to date precis of the chemistry and purposes of polyoxometalates with emphasis on new man made options directed in the direction of functionalized natural derivatives, self-assembly of mesoscopic composite polyoxoanions, new release of framework fabrics and skinny oxide motion pictures, prolonged optical, magnetic, and electric homes, functions in homogeneous and nanocluster-based catalysts, photocatalytic water decontamination, ribosomal crystallography, and topological points of huge symmetrical buildings.
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Extra resources for Polyoxometalate Chemistry From Topology via Self-Assembly to Applications
Klemperer, dans « Polyoxometalates : From Platonic Solids to Anti-Retroviral Activity », M. T. Pope, A. Müller Eds, Kluwer Academic Publishers, Dordrecht, The Netherlands, 1994 , p 87 ; (d) H. Akashi, J . Chen, T. Sakuraba, A. Yagasaki, Polyhedron, 1994, 13, 1091 ; (e) T. M. Che, V. W. Day, L. C. Francesconi, M. F. Fredrich, W. G. Klemperer, D. J. Main, A. Yagasaki, O. M. Yaghi, Inorg. , 1992, 31, 2920. 20. J. F. W. Keana, M. D. Ogan, J. Am. Chem. , 1986, 108, 7951 ; (b) J. F. W. Keana, M. D. -X.
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Despite its composition is quite similar to that of 15, 18 adopts a windmill-like structure rather that the fused triple-cubane-like structure of 15 (Figure 10). In figures 10 to 13, the Mo and W atoms are shown as hatched spheres while the Ru atoms are shown as dotted spheres. Fig. 10. Molecular structure of in .  and in 64 We recently undertook a study of the reactions of with molybdates and tungstates to examine the eventual influence of the synthesis conditions on the stoichiometry and the molecular structures of the resulting organometallic oxometal clusters.
Polyoxometalate Chemistry From Topology via Self-Assembly to Applications by M.T. Pope, Achim Müller