By E. Westhof (auth.), Prof. D. Vasilescu, Prof. J. Jaz, Prof. L. Packer, Prof. B. Pullman (eds.)
Water, Ions and Nucleic Acids.- Structural water of nucleic acids.- constitution of xenopus laevis 5s rRNA as made up our minds through resolution facts and desktop photograph modeling.- Ionic results on DNA electrostatic and elastic stability.- Copper ions at hint point and DNA functioning: stories played with 64Cu and 67Cu.- Z-DNA transconformation: a quantum molecular approach.- Proteins as counterions of DNA: a brand new version of nucleoprotamine structure.- influence of hydration and steel ions on DNA conformations studied by way of vibrational spectroscopy.- Showing-up the Na+ entropy of fluctuations through the DNA thermal transconformation by means of 23Na NMR: effect of radioprotector cysteamine.- Water, Ions and Proteins.- The critical helix of calmodulin and homologs — results of solvent publicity on stability.- regulate of protein kinase C functionality: an inhibitor study.- at the constitution and elasticity of elastin.- constitution and dynamics of a -19kD phosphoprotein, amelogenin, from bovine teeth enamel.- reports of protein hydration by means of direct NMR remark of person protein-bound water molecules.- a task for molecular movement as a mechanism for the NMR rest of water protons in organic systems.- impression of collagen crosslinking on collagen-water interaction.- Proton conductivity in hydrated proteins — facts for percolation.- A non-traditional function for water in the course of electron move by means of cytochrome C oxidase.- Water, Ions and Membranes.- Ion translocation via the NA,K-pump : correlation among electrogenic occasions and conformational transitions.- Theoretical and experimental elements of the explicit organization of monovalent ions with lipid bilayer membranes.- The position of isothermal enthalpy creation in coupled solute translocation around the membrane.- Intracellular spermine modifies neuronal electric activity.- Spectroscopic reports at the constitution and aggregation of calcium ionophore, A23187.- Fura-2 imaging of intracellular unfastened calcium dynamics in excitable cells.- Chemically pushed part separation in black lipid membranes.- A learn of cadmium and calcium delivery right into a marine unicellular alga.- Involvement of D2O for H2O substitution within the behaviour of a few excitable membranes.- Miscellaneous.- Femtosecond dynamics of unmarried electron move in aqueous media and mimetic versions of bioaggregates.- Bioelectrochemical houses of glutathione — A noise spectrography investigation.- taking into consideration the phone water homes for the cytochemical detection of cations: embedding into melamin after pyroantimonate fixation.
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Extra resources for Water and Ions in Biomolecular Systems: Proceedings of the 5th UNESCO International Conference
France SUMMARY: The polymorphism of nucleic acids is now well established and we know enough about the so-called Z-DNA form of left-handed helix to be able to undertake a quantum molecular approach of the various possible transconformations. This paper reports some of the first results we obtain by computations on our disugar-triphosphate model, essentially in the study of the varying conformations opened to the phosphate groups and the optimization of the forms named ZI and Zn. ,. ~ - - - - ---- Fig 1: Comparison of Band Z-DNA and details ....
We calculate the ionic free energy difference between the interwound and toroidal forms G (interwound) (~G G (toroidal)) as a funct ion of monovalent salt concentration. decreases ~G concentrat ion results and monotonically changes indicate that electrostatically strengths. This groups are, over the behavior on average, interwound form. 02 form toroidal interwound is increasing form expected, These M. is at salt favored low ionic since the phosphate more closely spaced in the compact Thus, our results show that the relative electrostatic stability of the toroidal and interwound forms with the same linking number is highly sensitive to changes in ionic strength.
0 nm for the Debye length at this ionic strength). Insertion of the numbers suggests that the buckling condition is easily satisfied in the DNA/null DNA system, and our conclusion about the local curvature of DNA with neutralized phosphate groups follows. Acknowledgement s; This work was supported by USPHS grants GM20861 (GSM) and GM34809 (WKO). ) would like to express her gratitude to Rutgers University for fellowship support during the past two years. Calculations were performed at the Rutgers Center for Computational Chemistry.
Water and Ions in Biomolecular Systems: Proceedings of the 5th UNESCO International Conference by E. Westhof (auth.), Prof. D. Vasilescu, Prof. J. Jaz, Prof. L. Packer, Prof. B. Pullman (eds.)